23-Electron Octahedral Molybdenum Cluster Complex [{Mo6I8}Cl6]−
نویسندگان
چکیده
منابع مشابه
Octahedral molybdenum cluster complexes with aromatic sulfonate ligands.
This article describes the synthesis, structures and systematic study of the spectroscopic and redox properties of a series of octahedral molybdenum metal cluster complexes with aromatic sulfonate ligands (nBu4N)2[{Mo6X8}(OTs)6] and (nBu4N)2[{Mo6X8}(PhSO3)6] (where X- is Cl-, Br- or I-; OTs- is p-toluenesulfonate and PhSO3- is benzenesulfonate). All the complexes demonstrated photoluminescence ...
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*Department of Metallurgy and Ceramics Science, Tokyo Institute of Technology, 2–12–1 Ookayama, Meguro, Tokyo 152–8551, Japan **National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan ***NIMS-Saint-Gobain Center of Excellence for Advanced Materials, National Institute for Materials Science, 1–1 Namiki, Tsukuba, Ibaraki 305–0044, Japan ****Institut des Sciences Chi...
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Complex Mo,V-based mixed oxides that crystallize in the orthorhombic M1-type structure are promising candidates for the selective oxidation of small alkanes. The oxygen sublattice of such a complex oxide has been studied by annular bright field scanning transmission electron microscopy. The recorded micrographs directly display the local distortion in the metal oxygen octahedra. From the degree...
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The hexavalent state, considered to be the highest oxidation level accessible for iron, has previously been found only in the tetrahedral ferrate dianion, FeO4(2-). We report the photochemical synthesis of another Fe(VI) compound, an octahedrally coordinated dication bearing a terminal nitrido ligand. Mössbauer and x-ray absorption spectra, supported by density functional theory, are consistent...
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ژورنال
عنوان ژورنال: Inorganic Chemistry
سال: 2017
ISSN: 0020-1669,1520-510X
DOI: 10.1021/acs.inorgchem.7b02760